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I love the action pose and motion you've got going on here! The shine on her sword really adds to the picture and shows just how gorgeous and graceful the attack is also! Rukia's fierce expression is also great, as you can tell that she's really serious haha~ I also love the shadows and the detailing on the bottom her shoe, it's really great!
The only thing about this picture though is that the way she has her body positioned seems kind of awkward...her top half is twisting over her foot, which makes sense but her left leg appears to extend way too far out.
Other than that..gosh the background details with the chains and shards are fantastic~ your art is lovely, keep up the fantastic work ^^